Find en forsker – Københavns Universitet

Precise and accurate δ13C analysis of rock samples using Flash Combustion–Cavity Ring Down Laser Spectroscopy

Research output: Contribution to journalJournal articleResearchpeer-review

David Morten Balslev-Clausen, Tais W. Dahl, Nabil Saad, Minik Thorleif Rosing

The ratio of 13C to 12C in marine sedimentary rocks holds important clues to the evolution of the carbon cycle through Earth history. Isotopic analyses are traditionally carried out using isotope ratio mass spectrometry (IRMS), but this technique is both labor-intensive, expensive and requires expert know-how. Here, we measure 13C/12C in natural sedimentary samples using Combustion Module - Cavity Ring Down Spectroscopy (CM-CRDS) with average precision and standard reproducibility of 0.05‰ and 0.2‰ (1 s.d., n = 17), respectively. The accuracy of the technique was determined from certified reference compounds to be <0.3‰. This is comparable to the performance using conventional mass spectrometry. We report data from a Cambrian succession of organic-rich shales straddling a positive d13Corg excursion of 2‰. We conclude that, optical determination of bulk organic d13C provides a high performance alternative to mass spectrometry and applicable for geochemical analyses.
Original languageEnglish
JournalJournal of Analytical Atomic Spectrometry
Issue number4
Pages (from-to)516-523
Number of pages8
StatePublished - 1 Apr 2013

ID: 43719659