Extraction across supported liquid membranes by use of electrical fields
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Extraction across supported liquid membranes by use of electrical fields. / Pedersen-Bjergaard, Stig; Rasmussen, Knut Einar.
I: Analytical and Bioanalytical Chemistry, Bind 388, Nr. 3, 01.06.2007, s. 521-523.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Extraction across supported liquid membranes by use of electrical fields
AU - Pedersen-Bjergaard, Stig
AU - Rasmussen, Knut Einar
PY - 2007/6/1
Y1 - 2007/6/1
N2 - The method of electrokinetic migration that used electrical fields to extract supported liquid membranes (SLM) was demonstrated. Several hydrophobic basic drug substances were extracted protonated molecules from a 300 μL acidic sample solution through a SLM, consisting 15 μL 2-nitropheynl octyl ether (NPOE) into 30 μL 10 mmol L-1hydrochloric acid (HCL) as the acceptor solution, applying 300 V dc. The electrical potential difference was the force driving extraction of the charged analytes, without any pH gradient across the SLM. The use of electrical potential difference was found to be a significant driving force for SLM extraction a pH gradient. The kinetic advantage of using electrical field was found also found to be significant, when extractions were performed from small sample volumes.
AB - The method of electrokinetic migration that used electrical fields to extract supported liquid membranes (SLM) was demonstrated. Several hydrophobic basic drug substances were extracted protonated molecules from a 300 μL acidic sample solution through a SLM, consisting 15 μL 2-nitropheynl octyl ether (NPOE) into 30 μL 10 mmol L-1hydrochloric acid (HCL) as the acceptor solution, applying 300 V dc. The electrical potential difference was the force driving extraction of the charged analytes, without any pH gradient across the SLM. The use of electrical potential difference was found to be a significant driving force for SLM extraction a pH gradient. The kinetic advantage of using electrical field was found also found to be significant, when extractions were performed from small sample volumes.
UR - http://www.scopus.com/inward/record.url?scp=34248182961&partnerID=8YFLogxK
U2 - 10.1007/s00216-007-1142-1
DO - 10.1007/s00216-007-1142-1
M3 - Journal article
C2 - 17285304
AN - SCOPUS:34248182961
VL - 388
SP - 521
EP - 523
JO - Analusis
JF - Analusis
SN - 0365-4877
IS - 3
ER -
ID: 231651215