Electronic Energy Levels and Optical Transitions in Samarium(III) Solvates
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Lanthanide luminescence fascinates with a complicated electronic structure and "forbidden" transitions. By studying the photophysics of lanthanide(III) solvates, a close to ideal average coordination geometry can be used to map both electronic energy levels and transition probabilities. Some lanthanide(III) ions are simpler to study than others, and samarium(III) belongs to the more difficult ones. The 4f5system has numerous absorption and emission lines in the visible and infrared parts of the spectrum and in this work, the energy levels giving rise to these transitions were mapped, the transition probability between them was calculated, and it was shown that the electronic structures of the samarium(III) solvates in DMSO, MeOH, and water are different.
Originalsprog | Engelsk |
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Tidsskrift | Journal of Physical Chemistry A |
Vol/bind | 126 |
Udgave nummer | 46 |
Sider (fra-til) | 8596-8605 |
Antal sider | 10 |
ISSN | 1089-5639 |
DOI | |
Status | Udgivet - 2022 |
Bibliografisk note
Funding Information:
The Villum Foundation grant #14922, the Carlsberg Foundation, and the University of Copenhagen.
Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.
ID: 328235107