Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths
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Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths. / Reinholdt, Anders; Bendix, Jesper.
I: Inorganic Chemistry, Bind 56, Nr. 20, 2017, s. 12492-12497.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths
AU - Reinholdt, Anders
AU - Bendix, Jesper
PY - 2017
Y1 - 2017
N2 - Functionalization of the terminal ruthenium carbide ligand in (Cy3P)2Cl2Ru≡C: with platinum and a range of ligands provides {Ru≡C−Pt−L} fragments with trans geometries. The bridging carbide exhibits chemical shifts and coupling constants to platinum, which are highly responsive to the degree of weakening of the RuC−Pt linkage induced by the trans ligands, making the terminal ruthenium carbide complex a sensitive probe for the electron donating abilities of other ligands.
AB - Functionalization of the terminal ruthenium carbide ligand in (Cy3P)2Cl2Ru≡C: with platinum and a range of ligands provides {Ru≡C−Pt−L} fragments with trans geometries. The bridging carbide exhibits chemical shifts and coupling constants to platinum, which are highly responsive to the degree of weakening of the RuC−Pt linkage induced by the trans ligands, making the terminal ruthenium carbide complex a sensitive probe for the electron donating abilities of other ligands.
U2 - 10.1021/acs.inorgchem.7b01956
DO - 10.1021/acs.inorgchem.7b01956
M3 - Journal article
C2 - 28945348
VL - 56
SP - 12492
EP - 12497
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 20
ER -
ID: 184633308