Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths

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Standard

Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths. / Reinholdt, Anders; Bendix, Jesper.

I: Inorganic Chemistry, Bind 56, Nr. 20, 2017, s. 12492-12497.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Reinholdt, A & Bendix, J 2017, 'Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths', Inorganic Chemistry, bind 56, nr. 20, s. 12492-12497. https://doi.org/10.1021/acs.inorgchem.7b01956

APA

Reinholdt, A., & Bendix, J. (2017). Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths. Inorganic Chemistry, 56(20), 12492-12497. https://doi.org/10.1021/acs.inorgchem.7b01956

Vancouver

Reinholdt A, Bendix J. Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths. Inorganic Chemistry. 2017;56(20):12492-12497. https://doi.org/10.1021/acs.inorgchem.7b01956

Author

Reinholdt, Anders ; Bendix, Jesper. / Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths. I: Inorganic Chemistry. 2017 ; Bind 56, Nr. 20. s. 12492-12497.

Bibtex

@article{e8cf8d8fe8d644d790b5944d4b8cc2e5,
title = "Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths",
abstract = "Functionalization of the terminal ruthenium carbide ligand in (Cy3P)2Cl2Ru≡C: with platinum and a range of ligands provides {Ru≡C−Pt−L} fragments with trans geometries. The bridging carbide exhibits chemical shifts and coupling constants to platinum, which are highly responsive to the degree of weakening of the RuC−Pt linkage induced by the trans ligands, making the terminal ruthenium carbide complex a sensitive probe for the electron donating abilities of other ligands.",
author = "Anders Reinholdt and Jesper Bendix",
year = "2017",
doi = "10.1021/acs.inorgchem.7b01956",
language = "English",
volume = "56",
pages = "12492--12497",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "20",

}

RIS

TY - JOUR

T1 - Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths

AU - Reinholdt, Anders

AU - Bendix, Jesper

PY - 2017

Y1 - 2017

N2 - Functionalization of the terminal ruthenium carbide ligand in (Cy3P)2Cl2Ru≡C: with platinum and a range of ligands provides {Ru≡C−Pt−L} fragments with trans geometries. The bridging carbide exhibits chemical shifts and coupling constants to platinum, which are highly responsive to the degree of weakening of the RuC−Pt linkage induced by the trans ligands, making the terminal ruthenium carbide complex a sensitive probe for the electron donating abilities of other ligands.

AB - Functionalization of the terminal ruthenium carbide ligand in (Cy3P)2Cl2Ru≡C: with platinum and a range of ligands provides {Ru≡C−Pt−L} fragments with trans geometries. The bridging carbide exhibits chemical shifts and coupling constants to platinum, which are highly responsive to the degree of weakening of the RuC−Pt linkage induced by the trans ligands, making the terminal ruthenium carbide complex a sensitive probe for the electron donating abilities of other ligands.

U2 - 10.1021/acs.inorgchem.7b01956

DO - 10.1021/acs.inorgchem.7b01956

M3 - Journal article

C2 - 28945348

VL - 56

SP - 12492

EP - 12497

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 20

ER -

ID: 184633308