Unequal sensitivities of energy levels in a high-symmetry Ho3+ complex towards lattice distortions

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Standard

Unequal sensitivities of energy levels in a high-symmetry Ho3+ complex towards lattice distortions. / Bonde, Niels A.; Appel, Markus; Ollivier, Jacques; Weihe, Hogni; Bendix, Jesper.

I: Chemical Communications, Bind 58, Nr. 53, 2022, s. 7431-7434.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Bonde, NA, Appel, M, Ollivier, J, Weihe, H & Bendix, J 2022, 'Unequal sensitivities of energy levels in a high-symmetry Ho3+ complex towards lattice distortions', Chemical Communications, bind 58, nr. 53, s. 7431-7434. https://doi.org/10.1039/d2cc02068h

APA

Bonde, N. A., Appel, M., Ollivier, J., Weihe, H., & Bendix, J. (2022). Unequal sensitivities of energy levels in a high-symmetry Ho3+ complex towards lattice distortions. Chemical Communications, 58(53), 7431-7434. https://doi.org/10.1039/d2cc02068h

Vancouver

Bonde NA, Appel M, Ollivier J, Weihe H, Bendix J. Unequal sensitivities of energy levels in a high-symmetry Ho3+ complex towards lattice distortions. Chemical Communications. 2022;58(53):7431-7434. https://doi.org/10.1039/d2cc02068h

Author

Bonde, Niels A. ; Appel, Markus ; Ollivier, Jacques ; Weihe, Hogni ; Bendix, Jesper. / Unequal sensitivities of energy levels in a high-symmetry Ho3+ complex towards lattice distortions. I: Chemical Communications. 2022 ; Bind 58, Nr. 53. s. 7431-7434.

Bibtex

@article{558970d80abc4602ade26ad77651d08e,
title = "Unequal sensitivities of energy levels in a high-symmetry Ho3+ complex towards lattice distortions",
abstract = "High-resolution inelastic neutron scattering has been used to study low-energy magnetic transitions in a Ho3+ complex. This complex crystallises in the high-symmetry space group P4/m and has near-perfect D-4d symmetry, which has allowed for the determination of all relevant spin-Hamiltonian parameters. Static and dynamic inhomogeneity in the crystal lattice manifests as a temperature-dependent broadening of the observed magnetic excitations. By implementing distributions in the spin-Hamiltonian parameters, it is possible to reproduce with great accuracy the observed magnetic transition spectrum. This reveals the range to which extraneous perturbations of the crystal field affect low-energy electronic states, such as those involved in quantum tunnelling of magnetisation, in atomic clock transitions, or in spintronics.",
keywords = "HETEROBIMETALLIC LANTERN COMPLEXES, SPIN QUBITS, RELAXATION, DESIGN",
author = "Bonde, {Niels A.} and Markus Appel and Jacques Ollivier and Hogni Weihe and Jesper Bendix",
year = "2022",
doi = "10.1039/d2cc02068h",
language = "English",
volume = "58",
pages = "7431--7434",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "53",

}

RIS

TY - JOUR

T1 - Unequal sensitivities of energy levels in a high-symmetry Ho3+ complex towards lattice distortions

AU - Bonde, Niels A.

AU - Appel, Markus

AU - Ollivier, Jacques

AU - Weihe, Hogni

AU - Bendix, Jesper

PY - 2022

Y1 - 2022

N2 - High-resolution inelastic neutron scattering has been used to study low-energy magnetic transitions in a Ho3+ complex. This complex crystallises in the high-symmetry space group P4/m and has near-perfect D-4d symmetry, which has allowed for the determination of all relevant spin-Hamiltonian parameters. Static and dynamic inhomogeneity in the crystal lattice manifests as a temperature-dependent broadening of the observed magnetic excitations. By implementing distributions in the spin-Hamiltonian parameters, it is possible to reproduce with great accuracy the observed magnetic transition spectrum. This reveals the range to which extraneous perturbations of the crystal field affect low-energy electronic states, such as those involved in quantum tunnelling of magnetisation, in atomic clock transitions, or in spintronics.

AB - High-resolution inelastic neutron scattering has been used to study low-energy magnetic transitions in a Ho3+ complex. This complex crystallises in the high-symmetry space group P4/m and has near-perfect D-4d symmetry, which has allowed for the determination of all relevant spin-Hamiltonian parameters. Static and dynamic inhomogeneity in the crystal lattice manifests as a temperature-dependent broadening of the observed magnetic excitations. By implementing distributions in the spin-Hamiltonian parameters, it is possible to reproduce with great accuracy the observed magnetic transition spectrum. This reveals the range to which extraneous perturbations of the crystal field affect low-energy electronic states, such as those involved in quantum tunnelling of magnetisation, in atomic clock transitions, or in spintronics.

KW - HETEROBIMETALLIC LANTERN COMPLEXES

KW - SPIN QUBITS

KW - RELAXATION

KW - DESIGN

U2 - 10.1039/d2cc02068h

DO - 10.1039/d2cc02068h

M3 - Journal article

C2 - 35698976

VL - 58

SP - 7431

EP - 7434

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 53

ER -

ID: 311885890