Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD): The first example of a heterobimetallic nitride-bridged complex containing chromium

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Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD) : The first example of a heterobimetallic nitride-bridged complex containing chromium. / Vibenholt, Johan; Magnussen, Magnus; Anthon, Christian; Bendix, Jesper.

I: Acta Crystallographica Section C: Crystal Structure Communications, Bind 66, Nr. 7, 16.07.2010, s. m177-m179.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Vibenholt, J, Magnussen, M, Anthon, C & Bendix, J 2010, 'Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD): The first example of a heterobimetallic nitride-bridged complex containing chromium', Acta Crystallographica Section C: Crystal Structure Communications, bind 66, nr. 7, s. m177-m179. https://doi.org/10.1107/S0108270110018238

APA

Vibenholt, J., Magnussen, M., Anthon, C., & Bendix, J. (2010). Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD): The first example of a heterobimetallic nitride-bridged complex containing chromium. Acta Crystallographica Section C: Crystal Structure Communications, 66(7), m177-m179. https://doi.org/10.1107/S0108270110018238

Vancouver

Vibenholt J, Magnussen M, Anthon C, Bendix J. Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD): The first example of a heterobimetallic nitride-bridged complex containing chromium. Acta Crystallographica Section C: Crystal Structure Communications. 2010 jul. 16;66(7):m177-m179. https://doi.org/10.1107/S0108270110018238

Author

Vibenholt, Johan ; Magnussen, Magnus ; Anthon, Christian ; Bendix, Jesper. / Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD) : The first example of a heterobimetallic nitride-bridged complex containing chromium. I: Acta Crystallographica Section C: Crystal Structure Communications. 2010 ; Bind 66, Nr. 7. s. m177-m179.

Bibtex

@article{43d94955f72e4706b42806e57af1a81e,
title = "Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD): The first example of a heterobimetallic nitride-bridged complex containing chromium",
abstract = "Five-coordinate Cr(N)(salen) {salen is 2,2′-[ethane-1,2- diylbis(nitrilo-methyl-idyne)]diphenolate} reacts with [RhCl(COD)]2 (COD is 1,5-cyclo-octa-diene) to yield the heterobimetallic nitride-bridged title compound, namely chlorido-2Cl-[2(η4)-1,5-cyclo-octa-diene] {2,2′-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-14 O,N,N′,O′} - nitrido-1:22 N:N-chromium(V)-rhodium(I), [CrRh(C16H14N2O2)ClN(C 8H12)]. The Cr - N bond of 1.5936 (14) {\AA} is elongated by only 0.035 {\AA} compared to the terminal Cr - N bond in the precursor. The nitride bridge is close to being linear [173.03 (9)°] and the Rh - N bond of 1.9594 (14) {\AA} is very short for a monodentate nitro-gen-donor ligand, indicating significant π-acceptor character of the Cr ≡ N group.",
author = "Johan Vibenholt and Magnus Magnussen and Christian Anthon and Jesper Bendix",
year = "2010",
month = jul,
day = "16",
doi = "10.1107/S0108270110018238",
language = "English",
volume = "66",
pages = "m177--m179",
journal = "Acta crystallographica. Section C, Structural chemistry",
issn = "2053-2296",
publisher = "Wiley",
number = "7",

}

RIS

TY - JOUR

T1 - Synthesis and mol-ecular structure of Cr(salen)(μ-N)RhCl(COD)

T2 - The first example of a heterobimetallic nitride-bridged complex containing chromium

AU - Vibenholt, Johan

AU - Magnussen, Magnus

AU - Anthon, Christian

AU - Bendix, Jesper

PY - 2010/7/16

Y1 - 2010/7/16

N2 - Five-coordinate Cr(N)(salen) {salen is 2,2′-[ethane-1,2- diylbis(nitrilo-methyl-idyne)]diphenolate} reacts with [RhCl(COD)]2 (COD is 1,5-cyclo-octa-diene) to yield the heterobimetallic nitride-bridged title compound, namely chlorido-2Cl-[2(η4)-1,5-cyclo-octa-diene] {2,2′-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-14 O,N,N′,O′} - nitrido-1:22 N:N-chromium(V)-rhodium(I), [CrRh(C16H14N2O2)ClN(C 8H12)]. The Cr - N bond of 1.5936 (14) Å is elongated by only 0.035 Å compared to the terminal Cr - N bond in the precursor. The nitride bridge is close to being linear [173.03 (9)°] and the Rh - N bond of 1.9594 (14) Å is very short for a monodentate nitro-gen-donor ligand, indicating significant π-acceptor character of the Cr ≡ N group.

AB - Five-coordinate Cr(N)(salen) {salen is 2,2′-[ethane-1,2- diylbis(nitrilo-methyl-idyne)]diphenolate} reacts with [RhCl(COD)]2 (COD is 1,5-cyclo-octa-diene) to yield the heterobimetallic nitride-bridged title compound, namely chlorido-2Cl-[2(η4)-1,5-cyclo-octa-diene] {2,2′-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-14 O,N,N′,O′} - nitrido-1:22 N:N-chromium(V)-rhodium(I), [CrRh(C16H14N2O2)ClN(C 8H12)]. The Cr - N bond of 1.5936 (14) Å is elongated by only 0.035 Å compared to the terminal Cr - N bond in the precursor. The nitride bridge is close to being linear [173.03 (9)°] and the Rh - N bond of 1.9594 (14) Å is very short for a monodentate nitro-gen-donor ligand, indicating significant π-acceptor character of the Cr ≡ N group.

U2 - 10.1107/S0108270110018238

DO - 10.1107/S0108270110018238

M3 - Journal article

AN - SCOPUS:77954519533

VL - 66

SP - m177-m179

JO - Acta crystallographica. Section C, Structural chemistry

JF - Acta crystallographica. Section C, Structural chemistry

SN - 2053-2296

IS - 7

ER -

ID: 240003172