Structural, electrochemical, and photophysical properties of gallium(III) 5, 10, 15-tris(pentafluorophenyl)corrole
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Structural, electrochemical, and photophysical properties of gallium(III) 5, 10, 15-tris(pentafluorophenyl)corrole. / Bendix, Jesper; Dmochowski, Ivan J.; Gray, Harry B.; Mahammed, Atif; Simkhovich, Liliya; Gross, Zeev.
I: Angewandte Chemie - International Edition, Bind 39, Nr. 22, 17.11.2000, s. 4048-4051.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Structural, electrochemical, and photophysical properties of gallium(III) 5, 10, 15-tris(pentafluorophenyl)corrole
AU - Bendix, Jesper
AU - Dmochowski, Ivan J.
AU - Gray, Harry B.
AU - Mahammed, Atif
AU - Simkhovich, Liliya
AU - Gross, Zeev
PY - 2000/11/17
Y1 - 2000/11/17
N2 - High quantum yields are found for the prototype metallocorrole 1, which is readily prepared from GaCl3 and tris(pentafluorophenyl)-corrole. The crystallographic and electronic structures of 1 are reported as well as the simple generation of its π-cation radical complex by chemical oxidation and the characteristic spectroscopic features of this ion.
AB - High quantum yields are found for the prototype metallocorrole 1, which is readily prepared from GaCl3 and tris(pentafluorophenyl)-corrole. The crystallographic and electronic structures of 1 are reported as well as the simple generation of its π-cation radical complex by chemical oxidation and the characteristic spectroscopic features of this ion.
KW - Corroles
KW - Density functional calculations
KW - Electronic structure
KW - Gallium
KW - Porphyrinoids
UR - http://www.scopus.com/inward/record.url?scp=0034680541&partnerID=8YFLogxK
U2 - 10.1002/1521-3773(20001117)39:22<4048::AID-ANIE4048>3.0.CO;2-7
DO - 10.1002/1521-3773(20001117)39:22<4048::AID-ANIE4048>3.0.CO;2-7
M3 - Journal article
AN - SCOPUS:0034680541
VL - 39
SP - 4048
EP - 4051
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 22
ER -
ID: 240003795