Structural, electrochemical, and photophysical properties of gallium(III) 5, 10, 15-tris(pentafluorophenyl)corrole

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

  • Bendix, Jesper
  • Ivan J. Dmochowski
  • Harry B. Gray
  • Atif Mahammed
  • Liliya Simkhovich
  • Zeev Gross

High quantum yields are found for the prototype metallocorrole 1, which is readily prepared from GaCl3 and tris(pentafluorophenyl)-corrole. The crystallographic and electronic structures of 1 are reported as well as the simple generation of its π-cation radical complex by chemical oxidation and the characteristic spectroscopic features of this ion.

TidsskriftAngewandte Chemie - International Edition
Udgave nummer22
Sider (fra-til)4048-4051
Antal sider4
StatusUdgivet - 17 nov. 2000

ID: 240003795