Magnetic interactions through fluoride: magnetic and spectroscopic characterization of discrete, linearly bridged [MnIII2(μ-F)F4(Me3tacn)2(PF6)

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Standard

Magnetic interactions through fluoride : magnetic and spectroscopic characterization of discrete, linearly bridged [MnIII2(μ-F)F4(Me3tacn)2(PF6). / Pedersen, Kasper Steen; Sigrist, Marc; Weihe, Høgni; Bond, Andrew; Thuesen, Christian Aagaard; Simonsen, Kim P.; Birk, Torben; Mutka, Hannu; Barra, Anne-Laure; Bendix, Jesper.

I: Inorganic Chemistry, Bind 53, Nr. 10, 2014, s. 5013-5019.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Pedersen, KS, Sigrist, M, Weihe, H, Bond, A, Thuesen, CA, Simonsen, KP, Birk, T, Mutka, H, Barra, A-L & Bendix, J 2014, 'Magnetic interactions through fluoride: magnetic and spectroscopic characterization of discrete, linearly bridged [MnIII2(μ-F)F4(Me3tacn)2(PF6)', Inorganic Chemistry, bind 53, nr. 10, s. 5013-5019. https://doi.org/10.1021/ic500049w

APA

Pedersen, K. S., Sigrist, M., Weihe, H., Bond, A., Thuesen, C. A., Simonsen, K. P., Birk, T., Mutka, H., Barra, A-L., & Bendix, J. (2014). Magnetic interactions through fluoride: magnetic and spectroscopic characterization of discrete, linearly bridged [MnIII2(μ-F)F4(Me3tacn)2(PF6). Inorganic Chemistry, 53(10), 5013-5019. https://doi.org/10.1021/ic500049w

Vancouver

Pedersen KS, Sigrist M, Weihe H, Bond A, Thuesen CA, Simonsen KP o.a. Magnetic interactions through fluoride: magnetic and spectroscopic characterization of discrete, linearly bridged [MnIII2(μ-F)F4(Me3tacn)2(PF6). Inorganic Chemistry. 2014;53(10):5013-5019. https://doi.org/10.1021/ic500049w

Author

Pedersen, Kasper Steen ; Sigrist, Marc ; Weihe, Høgni ; Bond, Andrew ; Thuesen, Christian Aagaard ; Simonsen, Kim P. ; Birk, Torben ; Mutka, Hannu ; Barra, Anne-Laure ; Bendix, Jesper. / Magnetic interactions through fluoride : magnetic and spectroscopic characterization of discrete, linearly bridged [MnIII2(μ-F)F4(Me3tacn)2(PF6). I: Inorganic Chemistry. 2014 ; Bind 53, Nr. 10. s. 5013-5019.

Bibtex

@article{ba5dc2ab11cd4e69b63e49464b5c1c20,
title = "Magnetic interactions through fluoride: magnetic and spectroscopic characterization of discrete, linearly bridged [MnIII2(μ-F)F4(Me3tacn)2(PF6)",
abstract = "The nature of the magnetic interaction through fluoride in a simple, dinuclear manganese(III) complex (1), bridged by a single fluoride ion in a perfectly linear fashion, is established by experiment and density functional theory. The magnitude of the antiferromagnetic exchange interaction and the manganese(III) zero-field-splitting parameters are unambiguously determined by inelastic neutron scattering to yield J = 33.0(2) cm(-1) (Ĥ = JŜ1·{\^S}2 Hamiltonian definition) and single-ion D = -4.0(1) cm(-1). Additionally, high-field, high-frequency electron paramagnetic resonance and magnetic measurements support the parameter values and resolve |E| ≈ 0.04 cm(-1). The exchange coupling constant (J) is 1 order of magnitude smaller than that found in comparable systems with linear oxide bridging but comparable to typical magnitudes through cyanide, thus underlining the potential of fluoride complexes as promising building blocks for novel magnetic systems.",
author = "Pedersen, {Kasper Steen} and Marc Sigrist and H{\o}gni Weihe and Andrew Bond and Thuesen, {Christian Aagaard} and Simonsen, {Kim P.} and Torben Birk and Hannu Mutka and Anne-Laure Barra and Jesper Bendix",
year = "2014",
doi = "10.1021/ic500049w",
language = "English",
volume = "53",
pages = "5013--5019",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "10",

}

RIS

TY - JOUR

T1 - Magnetic interactions through fluoride

T2 - magnetic and spectroscopic characterization of discrete, linearly bridged [MnIII2(μ-F)F4(Me3tacn)2(PF6)

AU - Pedersen, Kasper Steen

AU - Sigrist, Marc

AU - Weihe, Høgni

AU - Bond, Andrew

AU - Thuesen, Christian Aagaard

AU - Simonsen, Kim P.

AU - Birk, Torben

AU - Mutka, Hannu

AU - Barra, Anne-Laure

AU - Bendix, Jesper

PY - 2014

Y1 - 2014

N2 - The nature of the magnetic interaction through fluoride in a simple, dinuclear manganese(III) complex (1), bridged by a single fluoride ion in a perfectly linear fashion, is established by experiment and density functional theory. The magnitude of the antiferromagnetic exchange interaction and the manganese(III) zero-field-splitting parameters are unambiguously determined by inelastic neutron scattering to yield J = 33.0(2) cm(-1) (Ĥ = JŜ1·Ŝ2 Hamiltonian definition) and single-ion D = -4.0(1) cm(-1). Additionally, high-field, high-frequency electron paramagnetic resonance and magnetic measurements support the parameter values and resolve |E| ≈ 0.04 cm(-1). The exchange coupling constant (J) is 1 order of magnitude smaller than that found in comparable systems with linear oxide bridging but comparable to typical magnitudes through cyanide, thus underlining the potential of fluoride complexes as promising building blocks for novel magnetic systems.

AB - The nature of the magnetic interaction through fluoride in a simple, dinuclear manganese(III) complex (1), bridged by a single fluoride ion in a perfectly linear fashion, is established by experiment and density functional theory. The magnitude of the antiferromagnetic exchange interaction and the manganese(III) zero-field-splitting parameters are unambiguously determined by inelastic neutron scattering to yield J = 33.0(2) cm(-1) (Ĥ = JŜ1·Ŝ2 Hamiltonian definition) and single-ion D = -4.0(1) cm(-1). Additionally, high-field, high-frequency electron paramagnetic resonance and magnetic measurements support the parameter values and resolve |E| ≈ 0.04 cm(-1). The exchange coupling constant (J) is 1 order of magnitude smaller than that found in comparable systems with linear oxide bridging but comparable to typical magnitudes through cyanide, thus underlining the potential of fluoride complexes as promising building blocks for novel magnetic systems.

U2 - 10.1021/ic500049w

DO - 10.1021/ic500049w

M3 - Journal article

C2 - 24601580

VL - 53

SP - 5013

EP - 5019

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 10

ER -

ID: 120580044