Gelatinization dynamics of starch in dependence of its lamellar structure, crystalline polymorphs and amylose content
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Gelatinization dynamics of starch in dependence of its lamellar structure, crystalline polymorphs and amylose content. / Xu, Jinchuan; Blennow, Andreas; Li, Xiaoxi; Chen, Ling; Liu, Xingxun.
I: Carbohydrate Polymers, Bind 229, 115481, 01.02.2020, s. 1-11.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Gelatinization dynamics of starch in dependence of its lamellar structure, crystalline polymorphs and amylose content
AU - Xu, Jinchuan
AU - Blennow, Andreas
AU - Li, Xiaoxi
AU - Chen, Ling
AU - Liu, Xingxun
PY - 2020/2/1
Y1 - 2020/2/1
N2 - Structural dynamics of starch granules selected for different amylose content and crystalline type were analysed in excess water upon heating observed in-situ using SAXS and WAXS. The results showed that NMS and MBS exhibited higher degree of lamellar order than HAM. The peak width at half-maximum (FWHM) of HAM and NMS increased with temperature, demonstrating a gradual radial swelling of the lamellae during gelatinization. For NMS and HAM FWHM increased, suggesting that the dynamics of lamellar thicknesses of these starches were increased during hydrothermal compression exerted by the amorphous lamella. The decrease in FWHM found for MBS indicates that these lamellae were very vulnerable for dissolution. The changes in SAXS peak areas found for NMS and MBS were different from the areas of HAM indicating that A-type starch, as compared to B-type starch, possesses higher degree of lamellae ordering. Our data are potentially useful in starch-based materials processing.
AB - Structural dynamics of starch granules selected for different amylose content and crystalline type were analysed in excess water upon heating observed in-situ using SAXS and WAXS. The results showed that NMS and MBS exhibited higher degree of lamellar order than HAM. The peak width at half-maximum (FWHM) of HAM and NMS increased with temperature, demonstrating a gradual radial swelling of the lamellae during gelatinization. For NMS and HAM FWHM increased, suggesting that the dynamics of lamellar thicknesses of these starches were increased during hydrothermal compression exerted by the amorphous lamella. The decrease in FWHM found for MBS indicates that these lamellae were very vulnerable for dissolution. The changes in SAXS peak areas found for NMS and MBS were different from the areas of HAM indicating that A-type starch, as compared to B-type starch, possesses higher degree of lamellae ordering. Our data are potentially useful in starch-based materials processing.
KW - Crystallinity
KW - Gelatinization
KW - Multiscale structure
KW - Starch
KW - X-ray scattering
U2 - 10.1016/j.carbpol.2019.115481
DO - 10.1016/j.carbpol.2019.115481
M3 - Journal article
C2 - 31826407
AN - SCOPUS:85074356264
VL - 229
SP - 1
EP - 11
JO - Carbohydrate Polymers
JF - Carbohydrate Polymers
SN - 0144-8617
M1 - 115481
ER -
ID: 234148448