Four-site cooperative spin crossover in a mononuclear FeII complex
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Round and round: A mononuclear Fe(II) complex (see picture) with an N(4)S(2) coordination set has been characterized in four polymorphic forms. Two of the polymorphs display four-site cooperative spin crossover (SCO), shown conclusively by the crystal structure of a fully ordered 1:3 high-spin/low-spin state. The presence of S donor atoms in SCO-active compounds is unusual, and further investigation of Fe(II) complexes for SCO activity is warranted.
Originalsprog | Engelsk |
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Tidsskrift | Angewandte Chemie International Edition |
Vol/bind | 51 |
Udgave nummer | 44 |
Sider (fra-til) | 11049-11052 |
Antal sider | 4 |
ISSN | 1433-7851 |
DOI | |
Status | Udgivet - 2012 |
ID: 45763961