cis-Aquabis(2,2'-bipyridine-κ2N,N')-fluoridochromium(III) bis(perchlorate) dihydrate
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- cis-Aquabis(2,20-bipyridine-j2N,N0)- fluoridochromium(III) bis(perchlorate) dihydrate
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The title mixed aqua-fluoride complex, [CrF(C(10)H(8)N(2))(2)(H(2)O)](ClO(4))(2)·2H(2)O, has been synthesized by aqua-tion of the corresponding difluoride complex using lanthan-ide(III) ions as F(-) acceptors. The complex crystallizes with a Cr(III) ion at the center of a distorted octa-hedral coordination polyhedron with a cis arrangement of ligands. The crystal packing shows a hydrogen-bonding pattern involving water mol-ecules, the coordinated F atom and the perchlorate anions.
Originalsprog | Engelsk |
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Tidsskrift | Acta Crystallographica. Section E: Structure Reports Online |
Vol/bind | E66 |
Sider (fra-til) | m121-122 |
Antal sider | 2 |
ISSN | 1600-5368 |
DOI | |
Status | Udgivet - 2010 |
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