Ultraviolet absorption spectra and kinetics of acetonyl and acetonylperoxy radicals
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Ultraviolet absorption spectra and kinetics of acetonyl and acetonylperoxy radicals. / Cox, R. A.; Munk, Jette; Nielsen, Ole John; Pagsberg, Palle; Ratajczak, Emil.
In: Chemical Physics Letters, Vol. 173, No. 2-3, 05.10.1990, p. 206-210.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - Ultraviolet absorption spectra and kinetics of acetonyl and acetonylperoxy radicals
AU - Cox, R. A.
AU - Munk, Jette
AU - Nielsen, Ole John
AU - Pagsberg, Palle
AU - Ratajczak, Emil
PY - 1990/10/5
Y1 - 1990/10/5
N2 - Acetonyl radicals and acetonylperoxy radicals were produced by pulse radiolysis of gas mixtures with varying concentrations of CH3COCH3 and O2 in 1 atm of SF6 to initiate the reactions (1) F+CH3COCH3→HF+CH3COCH2, (2) 2CH3COCH2 → products, (3) CH3COCH2+O2(+M) → CH3COCH2O2(+M) and (4) 2CH3COCH2O2 → products. The ultraviolet absorption spectrum of the acetonyl radical is composed of a fairly weak band centered at 315 nm and a stronger band in the range of 200-250 nm. The absorption cross section has been determined, σ(310 nm) = (8.73 ± 0.50) × 10-19 cm2 molecule-1. The values k2=(4.8 ± 0.4) × 10-11, k3=(1.5 ± 0.3) × 10-12 and k4=(8.3 ± 1.6) × 10-12 cm3 molecule-1 s-1 at 298 K were derived by computer modelling of the observed kinetic features.
AB - Acetonyl radicals and acetonylperoxy radicals were produced by pulse radiolysis of gas mixtures with varying concentrations of CH3COCH3 and O2 in 1 atm of SF6 to initiate the reactions (1) F+CH3COCH3→HF+CH3COCH2, (2) 2CH3COCH2 → products, (3) CH3COCH2+O2(+M) → CH3COCH2O2(+M) and (4) 2CH3COCH2O2 → products. The ultraviolet absorption spectrum of the acetonyl radical is composed of a fairly weak band centered at 315 nm and a stronger band in the range of 200-250 nm. The absorption cross section has been determined, σ(310 nm) = (8.73 ± 0.50) × 10-19 cm2 molecule-1. The values k2=(4.8 ± 0.4) × 10-11, k3=(1.5 ± 0.3) × 10-12 and k4=(8.3 ± 1.6) × 10-12 cm3 molecule-1 s-1 at 298 K were derived by computer modelling of the observed kinetic features.
UR - http://www.scopus.com/inward/record.url?scp=0001474081&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(90)80079-S
DO - 10.1016/0009-2614(90)80079-S
M3 - Journal article
AN - SCOPUS:0001474081
VL - 173
SP - 206
EP - 210
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 2-3
ER -
ID: 214273226