Solvothermal synthesis of discrete cages and extended networks comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) building blocks

Research output: Contribution to journal › Journal article › Research › peer-review

Standard

Solvothermal synthesis of discrete cages and extended networks comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) building blocks. / Houton, Edel; Comar, Priyanka; Pitak, Mateusz B.; Coles, Simon J.; Ryder, Alan G.; Piligkos, Stergios; Brechin, Euan K.; Jones, Leigh F.

In: RSC Advances, Vol. 6, No. 77, 2016, p. 73668-73676.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Houton, E, Comar, P, Pitak, MB, Coles, SJ, Ryder, AG, Piligkos, S, Brechin, EK & Jones, LF 2016, 'Solvothermal synthesis of discrete cages and extended networks comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) building blocks', RSC Advances, vol. 6, no. 77, pp. 73668-73676. https://doi.org/10.1039/c6ra14811e

APA

Houton, E., Comar, P., Pitak, M. B., Coles, S. J., Ryder, A. G., Piligkos, S., Brechin, E. K., & Jones, L. F. (2016). Solvothermal synthesis of discrete cages and extended networks comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) building blocks. RSC Advances, 6(77), 73668-73676. https://doi.org/10.1039/c6ra14811e

Vancouver

Houton E, Comar P, Pitak MB, Coles SJ, Ryder AG, Piligkos S et al. Solvothermal synthesis of discrete cages and extended networks comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) building blocks. RSC Advances. 2016;6(77):73668-73676. https://doi.org/10.1039/c6ra14811e

Author

Houton, Edel ; Comar, Priyanka ; Pitak, Mateusz B. ; Coles, Simon J. ; Ryder, Alan G. ; Piligkos, Stergios ; Brechin, Euan K. ; Jones, Leigh F. / Solvothermal synthesis of discrete cages and extended networks comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) building blocks. In: RSC Advances. 2016 ; Vol. 6, No. 77. pp. 73668-73676.

Bibtex

@article{be1c3383af4a4a96aa759fb717ca73ad,
title = "Solvothermal synthesis of discrete cages and extended networks comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) building blocks",
abstract = "The synthesis, structural and magnetic characterisation of a family of related Cr(iii) cages are reported. Each member comprises {Cr(iii)3O(O2CR1)3(R2-sao)3}2- (R1 = H, CH3, C(CH3)3, C14H9; R2 = Me, Ph, tBu, C10H8) triangles linked by Na+ cations, resulting in either the discrete complexes [H3O][NEt4]2[NaCr(iii)6O2(O2C-C14H9)6(Naphth-sao)6] (1) and [Na4Cr(iii)6O2(O2CC(CH3)3)6(3,5-di-tBu-sao)6(MeCN)6] (3); or the extended networks [H3O]2[Na2Cr(iii)6O2(O2CH)6(Ph-sao)6(MeCN)2(H2O)2]n·4MeCN (2); [H3O][Na3Cr(iii)6O2(O2CCH3)6(Me-sao)6(MeCN)]n (4) and [Na2Cr(iii)3O(O2CCH3)3(Me-sao)3(H2O)6]n·3MeCN (5). Magnetic susceptibility data obtained for 2 and 4 reveal weak antiferromagnetic exchange between the Cr(iii) ions in the triangles.",
author = "Edel Houton and Priyanka Comar and Pitak, {Mateusz B.} and Coles, {Simon J.} and Ryder, {Alan G.} and Stergios Piligkos and Brechin, {Euan K.} and Jones, {Leigh F.}",
year = "2016",
doi = "10.1039/c6ra14811e",
language = "English",
volume = "6",
pages = "73668--73676",
journal = "RSC Advances",
issn = "2046-2069",
publisher = "RSC Publishing",
number = "77",

}

RIS

TY - JOUR

T1 - Solvothermal synthesis of discrete cages and extended networks comprising {Cr(III)3O(O2CR)3(oxime)3}2- (R = H, CH3, C(CH3)3, C14H9) building blocks

AU - Houton, Edel

AU - Comar, Priyanka

AU - Pitak, Mateusz B.

AU - Coles, Simon J.

AU - Ryder, Alan G.

AU - Piligkos, Stergios

AU - Brechin, Euan K.

AU - Jones, Leigh F.

PY - 2016

Y1 - 2016

N2 - The synthesis, structural and magnetic characterisation of a family of related Cr(iii) cages are reported. Each member comprises {Cr(iii)3O(O2CR1)3(R2-sao)3}2- (R1 = H, CH3, C(CH3)3, C14H9; R2 = Me, Ph, tBu, C10H8) triangles linked by Na+ cations, resulting in either the discrete complexes [H3O][NEt4]2[NaCr(iii)6O2(O2C-C14H9)6(Naphth-sao)6] (1) and [Na4Cr(iii)6O2(O2CC(CH3)3)6(3,5-di-tBu-sao)6(MeCN)6] (3); or the extended networks [H3O]2[Na2Cr(iii)6O2(O2CH)6(Ph-sao)6(MeCN)2(H2O)2]n·4MeCN (2); [H3O][Na3Cr(iii)6O2(O2CCH3)6(Me-sao)6(MeCN)]n (4) and [Na2Cr(iii)3O(O2CCH3)3(Me-sao)3(H2O)6]n·3MeCN (5). Magnetic susceptibility data obtained for 2 and 4 reveal weak antiferromagnetic exchange between the Cr(iii) ions in the triangles.

AB - The synthesis, structural and magnetic characterisation of a family of related Cr(iii) cages are reported. Each member comprises {Cr(iii)3O(O2CR1)3(R2-sao)3}2- (R1 = H, CH3, C(CH3)3, C14H9; R2 = Me, Ph, tBu, C10H8) triangles linked by Na+ cations, resulting in either the discrete complexes [H3O][NEt4]2[NaCr(iii)6O2(O2C-C14H9)6(Naphth-sao)6] (1) and [Na4Cr(iii)6O2(O2CC(CH3)3)6(3,5-di-tBu-sao)6(MeCN)6] (3); or the extended networks [H3O]2[Na2Cr(iii)6O2(O2CH)6(Ph-sao)6(MeCN)2(H2O)2]n·4MeCN (2); [H3O][Na3Cr(iii)6O2(O2CCH3)6(Me-sao)6(MeCN)]n (4) and [Na2Cr(iii)3O(O2CCH3)3(Me-sao)3(H2O)6]n·3MeCN (5). Magnetic susceptibility data obtained for 2 and 4 reveal weak antiferromagnetic exchange between the Cr(iii) ions in the triangles.

U2 - 10.1039/c6ra14811e

DO - 10.1039/c6ra14811e

M3 - Journal article

AN - SCOPUS:84981349670

VL - 6

SP - 73668

EP - 73676

JO - RSC Advances

JF - RSC Advances

SN - 2046-2069

IS - 77

ER -

ID: 169728886