Derivatives of trigonal lanthanide complexes by reaction with long aliphatic chain amines
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We present the synthesis and characterisation of a novel series of lanthanide complexes bearing long aliphatic chains, obtained by post-functionalisation of LnL (Ln = Tb–Tm and Y, H3L = tris(((3-formyl-5-methylsalicylidene)amine)ethyl)amine) via Schiff-base reaction with 1-octadecylamine. Crystal structures show that the first coordination sphere is not radically perturbed by the post-functionalisation although the trigonal symmetry is lost. Post-derivatisation influences the static magnetic properties of the Kramers and non-Kramers ions differently, with the non-Kramers ions most sensitive to derivatisation. The observed differences likely stem from changes in eigenvector composition as luminescence spectra showed minor modifications of the energy spectra upon derivatisation.
Original language | English |
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Journal | Comptes Rendus Chimie |
Volume | 27 |
Issue number | S1 |
Number of pages | 12 |
ISSN | 1631-0748 |
DOIs | |
Publication status | Published - 2024 |
Bibliographical note
Funding Information:
We thank the Novo Nordisk Foundation for research grant NNF20OC0065610.
Funding Information:
Keywords. Lanthanide complexes, Aliphatic chains, Magnetic properties, Crystal structure, Crystal field. Funding. Novo Nordisk Foundation (Grant agreement no. NNF20OC0065610).
Publisher Copyright:
© 2024 Academie des sciences. All rights reserved.
- Aliphatic chains, Crystal field, Crystal structure, Lanthanide complexes, Magnetic properties
Research areas
ID: 397906284