A study of the DIBAL-promoted selective debenzylation of alpha-cyclodextrin protected with two different benzyl groups
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An alpha-cyclodextrin protected with 2,4-dichlorobenzyl groups on the primary alcohols and ordinary benzyl groups on the secondary alcohols was prepared and subjected to DIBAL (diisobutylaluminum hydride)-promoted selective debenzylation. Debenzylation proceeded by first removing two dichlorobenzyl groups from the 6A,D positions and then removing one or two benzyl groups from the 3A,D positions.
Original language | English |
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Journal | Beilstein Journal of Organic Chemistry |
Volume | 18 |
Pages (from-to) | 1553-1559 |
Number of pages | 7 |
ISSN | 1860-5397 |
DOIs | |
Publication status | Published - 17 Nov 2022 |
- aluminum hydrides, cyclodextrin, debenzylation, 2, 4-dichlorobenzyl, selective, POWERFUL, SUGARS
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