Twisted molecular magnets

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Standard

Twisted molecular magnets. / Inglis, Ross; Milios, Constantinos J.; Jones, Leigh F.; Piligkos, Stergios; Brechin, Euan K.

I: Chemical Communications, Bind 48, Nr. 2, 2012, s. 181-190.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Inglis, R, Milios, CJ, Jones, LF, Piligkos, S & Brechin, EK 2012, 'Twisted molecular magnets', Chemical Communications, bind 48, nr. 2, s. 181-190. https://doi.org/10.1039/c1cc13558a

APA

Inglis, R., Milios, C. J., Jones, L. F., Piligkos, S., & Brechin, E. K. (2012). Twisted molecular magnets. Chemical Communications, 48(2), 181-190. https://doi.org/10.1039/c1cc13558a

Vancouver

Inglis R, Milios CJ, Jones LF, Piligkos S, Brechin EK. Twisted molecular magnets. Chemical Communications. 2012;48(2):181-190. https://doi.org/10.1039/c1cc13558a

Author

Inglis, Ross ; Milios, Constantinos J. ; Jones, Leigh F. ; Piligkos, Stergios ; Brechin, Euan K. / Twisted molecular magnets. I: Chemical Communications. 2012 ; Bind 48, Nr. 2. s. 181-190.

Bibtex

@article{cfdfc3c63c714bdbaf790d5806c913bd,

title = "Twisted molecular magnets",

abstract = "The use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of a family of approximately fifty hexanuclear ([Mn(III)(6)]) and thirty trinuclear ([Mn(III)(3)]) Single-Molecule Magnets (SMMs). Deliberate, targeted structural distortion of the metallic core afforded family members with increasingly puckered configurations, leading to a switch in the pairwise magnetic exchange from antiferromagnetic to ferromagnetic. Examination of both the structural and magnetic data revealed a semi-quantitative magneto-structural correlation, from which the factors governing the magnetic properties could be extracted and used for predicting the properties of new family members and even more complicated structures containing analogous building blocks. Herein we describe an overview of this extensive body of work and discuss its potential impact on similar systems.",

author = "Ross Inglis and Milios, {Constantinos J.} and Jones, {Leigh F.} and Stergios Piligkos and Brechin, {Euan K.}",

note = "This journal is {\textcopyright} The Royal Society of Chemistry 2012",

year = "2012",

doi = "10.1039/c1cc13558a",

language = "English",

volume = "48",

pages = "181--190",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "2",

}

RIS

TY - JOUR

T1 - Twisted molecular magnets

AU - Inglis, Ross

AU - Milios, Constantinos J.

AU - Jones, Leigh F.

AU - Piligkos, Stergios

AU - Brechin, Euan K.

PY - 2012

Y1 - 2012

N2 - The use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of a family of approximately fifty hexanuclear ([Mn(III)(6)]) and thirty trinuclear ([Mn(III)(3)]) Single-Molecule Magnets (SMMs). Deliberate, targeted structural distortion of the metallic core afforded family members with increasingly puckered configurations, leading to a switch in the pairwise magnetic exchange from antiferromagnetic to ferromagnetic. Examination of both the structural and magnetic data revealed a semi-quantitative magneto-structural correlation, from which the factors governing the magnetic properties could be extracted and used for predicting the properties of new family members and even more complicated structures containing analogous building blocks. Herein we describe an overview of this extensive body of work and discuss its potential impact on similar systems.

AB - The use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of a family of approximately fifty hexanuclear ([Mn(III)(6)]) and thirty trinuclear ([Mn(III)(3)]) Single-Molecule Magnets (SMMs). Deliberate, targeted structural distortion of the metallic core afforded family members with increasingly puckered configurations, leading to a switch in the pairwise magnetic exchange from antiferromagnetic to ferromagnetic. Examination of both the structural and magnetic data revealed a semi-quantitative magneto-structural correlation, from which the factors governing the magnetic properties could be extracted and used for predicting the properties of new family members and even more complicated structures containing analogous building blocks. Herein we describe an overview of this extensive body of work and discuss its potential impact on similar systems.

U2 - 10.1039/c1cc13558a

DO - 10.1039/c1cc13558a

M3 - Journal article

C2 - 21892459

VL - 48

SP - 181

EP - 190

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 2

ER -

ID: 45764238