Twisted molecular magnets
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Standard
Twisted molecular magnets. / Inglis, Ross; Milios, Constantinos J.; Jones, Leigh F.; Piligkos, Stergios; Brechin, Euan K.
I: Chemical Communications, Bind 48, Nr. 2, 2012, s. 181-190.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Harvard
APA
Vancouver
Author
Bibtex
}
RIS
TY - JOUR
T1 - Twisted molecular magnets
AU - Inglis, Ross
AU - Milios, Constantinos J.
AU - Jones, Leigh F.
AU - Piligkos, Stergios
AU - Brechin, Euan K.
N1 - This journal is © The Royal Society of Chemistry 2012
PY - 2012
Y1 - 2012
N2 - The use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of a family of approximately fifty hexanuclear ([Mn(III)(6)]) and thirty trinuclear ([Mn(III)(3)]) Single-Molecule Magnets (SMMs). Deliberate, targeted structural distortion of the metallic core afforded family members with increasingly puckered configurations, leading to a switch in the pairwise magnetic exchange from antiferromagnetic to ferromagnetic. Examination of both the structural and magnetic data revealed a semi-quantitative magneto-structural correlation, from which the factors governing the magnetic properties could be extracted and used for predicting the properties of new family members and even more complicated structures containing analogous building blocks. Herein we describe an overview of this extensive body of work and discuss its potential impact on similar systems.
AB - The use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of a family of approximately fifty hexanuclear ([Mn(III)(6)]) and thirty trinuclear ([Mn(III)(3)]) Single-Molecule Magnets (SMMs). Deliberate, targeted structural distortion of the metallic core afforded family members with increasingly puckered configurations, leading to a switch in the pairwise magnetic exchange from antiferromagnetic to ferromagnetic. Examination of both the structural and magnetic data revealed a semi-quantitative magneto-structural correlation, from which the factors governing the magnetic properties could be extracted and used for predicting the properties of new family members and even more complicated structures containing analogous building blocks. Herein we describe an overview of this extensive body of work and discuss its potential impact on similar systems.
U2 - 10.1039/c1cc13558a
DO - 10.1039/c1cc13558a
M3 - Journal article
C2 - 21892459
VL - 48
SP - 181
EP - 190
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 2
ER -
ID: 45764238