Single-molecule magnet engineering: building-block approaches
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Single-molecule magnet engineering : building-block approaches. / Pedersen, Kasper Steen; Bendix, Jesper; Clérac, Rodolphe.
I: Chemical Communications, Bind 50, Nr. 34, 2014, s. 4396-4415.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Single-molecule magnet engineering
T2 - building-block approaches
AU - Pedersen, Kasper Steen
AU - Bendix, Jesper
AU - Clérac, Rodolphe
PY - 2014
Y1 - 2014
N2 - Tailoring the specific magnetic properties of any material relies on the topological control of the constituent metal ion building blocks. Although this general approach does not seem to be easily applied to traditional inorganic bulk magnets, coordination chemistry offers a unique tool to delicately tune, for instance, the properties of molecules that behave as "magnets", the so-called single-molecule magnets (SMMs). Although many interesting SMMs have been prepared by a more or less serendipitous approach, the assembly of predesigned, isolatable molecular entities into higher nuclearity complexes constitutes an elegant and fascinating strategy. This Feature article focuses on the use of building blocks or modules (both terms being used indiscriminately) to direct the structure, and therefore also the magnetic properties, of metal ion complexes exhibiting SMM behaviour. This journal is
AB - Tailoring the specific magnetic properties of any material relies on the topological control of the constituent metal ion building blocks. Although this general approach does not seem to be easily applied to traditional inorganic bulk magnets, coordination chemistry offers a unique tool to delicately tune, for instance, the properties of molecules that behave as "magnets", the so-called single-molecule magnets (SMMs). Although many interesting SMMs have been prepared by a more or less serendipitous approach, the assembly of predesigned, isolatable molecular entities into higher nuclearity complexes constitutes an elegant and fascinating strategy. This Feature article focuses on the use of building blocks or modules (both terms being used indiscriminately) to direct the structure, and therefore also the magnetic properties, of metal ion complexes exhibiting SMM behaviour. This journal is
U2 - 10.1039/c4cc00339j
DO - 10.1039/c4cc00339j
M3 - Journal article
C2 - 24626635
AN - SCOPUS:84897567171
VL - 50
SP - 4396
EP - 4415
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 34
ER -
ID: 130983234