In-depth magnetic characterization of a [2 × 2] Mn(III) square grid using SQUID magnetometry, inelastic neutron scattering, and high-field electron paramagnetic resonance spectroscopy
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In-depth magnetic characterization of a [2 × 2] Mn(III) square grid using SQUID magnetometry, inelastic neutron scattering, and high-field electron paramagnetic resonance spectroscopy. / Konstantatos, Andreas; Bewley, Robert; Barra, Anne Laure; Bendix, Jesper; Piligkos, Stergios; Weihe, Høgni.
I: Inorganic Chemistry, Bind 55, Nr. 20, 2016, s. 10377-10382.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - In-depth magnetic characterization of a [2 × 2] Mn(III) square grid using SQUID magnetometry, inelastic neutron scattering, and high-field electron paramagnetic resonance spectroscopy
AU - Konstantatos, Andreas
AU - Bewley, Robert
AU - Barra, Anne Laure
AU - Bendix, Jesper
AU - Piligkos, Stergios
AU - Weihe, Høgni
PY - 2016
Y1 - 2016
N2 - A tetranuclear [2 × 2] grid-like manganese(III) Schiff base complex, Mn4, has been synthesized and characterized by single-crystal X-ray crystallography. Direct-current magnetization measurements were performed on the system and proved to be insufficient for an accurate magnetic model to be deduced. Combined inelastic neutron scattering (INS) and electron paramagnetic resonance (EPR) experiments provided the necessary information in order to successfully model the magnetic properties of Mn4. The resulting model takes into account both the magnitude and the relative orientations of the single-ion anisotropy tensors.
AB - A tetranuclear [2 × 2] grid-like manganese(III) Schiff base complex, Mn4, has been synthesized and characterized by single-crystal X-ray crystallography. Direct-current magnetization measurements were performed on the system and proved to be insufficient for an accurate magnetic model to be deduced. Combined inelastic neutron scattering (INS) and electron paramagnetic resonance (EPR) experiments provided the necessary information in order to successfully model the magnetic properties of Mn4. The resulting model takes into account both the magnitude and the relative orientations of the single-ion anisotropy tensors.
U2 - 10.1021/acs.inorgchem.6b01634
DO - 10.1021/acs.inorgchem.6b01634
M3 - Journal article
C2 - 27670363
AN - SCOPUS:84992110702
VL - 55
SP - 10377
EP - 10382
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 20
ER -
ID: 170764992