Homogeneous RuCl 2 (PPh 3 ) 3 -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor
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Homogeneous RuCl 2 (PPh 3 ) 3 -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor. / Mukhopadhyay, Sudip; Yaghmur, Anan; Benichou, Axel; Sasson, Yoel.
I: Organic Process Research and Development, Bind 4, Nr. 6, 01.11.2000, s. 571-574.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Homogeneous RuCl 2 (PPh 3 ) 3 -catalyzed regioselective liquid-phase transfer hydrogenation of carbon-carbon double bond in chlorobenzylidene ketones with ethylene glycol as hydrogen donor
AU - Mukhopadhyay, Sudip
AU - Yaghmur, Anan
AU - Benichou, Axel
AU - Sasson, Yoel
PY - 2000/11/1
Y1 - 2000/11/1
N2 - The regioselective transfer hydrogenation of a carbon-carbon double bond of different chlorobenzylidene ketones is effectuated in ethylene glycol with a very high selectivity in the presence of homogeneous, tris(triphenylphosphine)ruthenium-(II) chloride catalyst. Different important process parameters such as temperature, catalyst loading, and reaction period are studied. The reaction follows a first-order kinetics, and the energy of activation was found to be 52 kJ/mol.
AB - The regioselective transfer hydrogenation of a carbon-carbon double bond of different chlorobenzylidene ketones is effectuated in ethylene glycol with a very high selectivity in the presence of homogeneous, tris(triphenylphosphine)ruthenium-(II) chloride catalyst. Different important process parameters such as temperature, catalyst loading, and reaction period are studied. The reaction follows a first-order kinetics, and the energy of activation was found to be 52 kJ/mol.
UR - http://www.scopus.com/inward/record.url?scp=0034345920&partnerID=8YFLogxK
M3 - Journal article
AN - SCOPUS:0034345920
VL - 4
SP - 571
EP - 574
JO - Organic Process Research and Development
JF - Organic Process Research and Development
SN - 1083-6160
IS - 6
ER -
ID: 221830117