Electronic Raman transitions from the vanadium(III) hexa-aqua cation, in guanidinium vanadium sulphate
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Electronic Raman transitions from the vanadium(III) hexa-aqua cation, in guanidinium vanadium sulphate. / Spichiger, David; Carver, Graham; Dobe, Christopher; Bendix, Jesper; Tregenna-Piggott, Philip L.W.; Meier, Roland; Zahn, Gernot.
I: Chemical Physics Letters, Bind 337, Nr. 4-6, 06.04.2001, s. 391-397.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Electronic Raman transitions from the vanadium(III) hexa-aqua cation, in guanidinium vanadium sulphate
AU - Spichiger, David
AU - Carver, Graham
AU - Dobe, Christopher
AU - Bendix, Jesper
AU - Tregenna-Piggott, Philip L.W.
AU - Meier, Roland
AU - Zahn, Gernot
PY - 2001/4/6
Y1 - 2001/4/6
N2 - Electronic Raman transitions (3A→3E(C3)) have been observed between the trigonally split components of the 3T1g(Oh) ground term of the vanadium(III) hexa-aqua cation in guanidinium vanadium sulphate hexa-hydrate. The magnitude of the trigonal field splitting is considerable, ~2720 cm-1, which is consistent with expectations based on the stereochemistry of the [V(OH2)6]3+ complex. It is shown that a satisfactory reproduction of the electronic Raman band profile can be obtained only by assuming a (3A⊕3E)⊗e vibronic coupling model.
AB - Electronic Raman transitions (3A→3E(C3)) have been observed between the trigonally split components of the 3T1g(Oh) ground term of the vanadium(III) hexa-aqua cation in guanidinium vanadium sulphate hexa-hydrate. The magnitude of the trigonal field splitting is considerable, ~2720 cm-1, which is consistent with expectations based on the stereochemistry of the [V(OH2)6]3+ complex. It is shown that a satisfactory reproduction of the electronic Raman band profile can be obtained only by assuming a (3A⊕3E)⊗e vibronic coupling model.
UR - http://www.scopus.com/inward/record.url?scp=0000613558&partnerID=8YFLogxK
U2 - 10.1016/S0009-2614(01)00220-2
DO - 10.1016/S0009-2614(01)00220-2
M3 - Journal article
AN - SCOPUS:0000613558
VL - 337
SP - 391
EP - 397
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 4-6
ER -
ID: 240003570