Diastereoisomeric β-ethyl aspartate-cobalt(III) complexes: Δ (+)578- and Δ (-)578--bis-(ethane-1,2-diamine) [β-ethyl (S)-aspartato]cobalt(III) bis-(perchlorate) monohydrate

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Standard

Diastereoisomeric β-ethyl aspartate-cobalt(III) complexes : Δ (+)578- and Δ (-)578--bis-(ethane-1,2-diamine) [β-ethyl (S)-aspartato]cobalt(III) bis-(perchlorate) monohydrate. / Hammershoøi, Anders; Schau-Magnussen, Magnus; Bendix, Jesper; Moølgaard, Anne.

I: Acta Crystallographica Section C: Crystal Structure Communications, Bind 66, Nr. 11, 2010, s. m319-m322.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Hammershoøi, A, Schau-Magnussen, M, Bendix, J & Moølgaard, A 2010, 'Diastereoisomeric β-ethyl aspartate-cobalt(III) complexes: Δ (+)578- and Δ (-)578--bis-(ethane-1,2-diamine) [β-ethyl (S)-aspartato]cobalt(III) bis-(perchlorate) monohydrate', Acta Crystallographica Section C: Crystal Structure Communications, bind 66, nr. 11, s. m319-m322. https://doi.org/10.1107/S0108270110036851

APA

Hammershoøi, A., Schau-Magnussen, M., Bendix, J., & Moølgaard, A. (2010). Diastereoisomeric β-ethyl aspartate-cobalt(III) complexes: Δ (+)578- and Δ (-)578--bis-(ethane-1,2-diamine) [β-ethyl (S)-aspartato]cobalt(III) bis-(perchlorate) monohydrate. Acta Crystallographica Section C: Crystal Structure Communications, 66(11), m319-m322. https://doi.org/10.1107/S0108270110036851

Vancouver

Hammershoøi A, Schau-Magnussen M, Bendix J, Moølgaard A. Diastereoisomeric β-ethyl aspartate-cobalt(III) complexes: Δ (+)578- and Δ (-)578--bis-(ethane-1,2-diamine) [β-ethyl (S)-aspartato]cobalt(III) bis-(perchlorate) monohydrate. Acta Crystallographica Section C: Crystal Structure Communications. 2010;66(11):m319-m322. https://doi.org/10.1107/S0108270110036851

Author

Hammershoøi, Anders ; Schau-Magnussen, Magnus ; Bendix, Jesper ; Moølgaard, Anne. / Diastereoisomeric β-ethyl aspartate-cobalt(III) complexes : Δ (+)578- and Δ (-)578--bis-(ethane-1,2-diamine) [β-ethyl (S)-aspartato]cobalt(III) bis-(perchlorate) monohydrate. I: Acta Crystallographica Section C: Crystal Structure Communications. 2010 ; Bind 66, Nr. 11. s. m319-m322.

Bibtex

@article{d55ddd3dbfd64f479887a1c247842e2d,
title = "Diastereoisomeric β-ethyl aspartate-cobalt(III) complexes: Δ (+)578- and Δ (-)578--bis-(ethane-1,2-diamine) [β-ethyl (S)-aspartato]cobalt(III) bis-(perchlorate) monohydrate",
abstract = "The structures of the diastereoisomers Δ (+)578-, (I), andΔ(-)578--bis-(ethane-1,2-diamine)[β-ethyl (S)-aspartato-k2 N,O1]cobalt(III) bis-(perchlorate) monohydrate, (II), both [Co(C6H10N2O 4)(C2H8N2)2](ClO 4)2·H2O, are compared. In both structures, the ester group of the amino acid side chain is engaged only in intra-molecular hydrogen bonding to coordinated amine groups. This inter-action is stronger in (I) and correlates with previously observed diastereoisomeric equilibrium ratios for related metal complex systems in aqueous media. The two perchlorate anions of (II) are located on twofold axes. Both perchlorates in (I) and one of the perchlorates in (II) are affected by disorder. Both structures exhibit extensive three-dimensional hydrogen-bonding net-works.",
author = "Anders Hammersho{\o}i and Magnus Schau-Magnussen and Jesper Bendix and Anne Mo{\o}lgaard",
year = "2010",
doi = "10.1107/S0108270110036851",
language = "English",
volume = "66",
pages = "m319--m322",
journal = "Acta crystallographica. Section C, Structural chemistry",
issn = "2053-2296",
publisher = "Wiley",
number = "11",

}

RIS

TY - JOUR

T1 - Diastereoisomeric β-ethyl aspartate-cobalt(III) complexes

T2 - Δ (+)578- and Δ (-)578--bis-(ethane-1,2-diamine) [β-ethyl (S)-aspartato]cobalt(III) bis-(perchlorate) monohydrate

AU - Hammershoøi, Anders

AU - Schau-Magnussen, Magnus

AU - Bendix, Jesper

AU - Moølgaard, Anne

PY - 2010

Y1 - 2010

N2 - The structures of the diastereoisomers Δ (+)578-, (I), andΔ(-)578--bis-(ethane-1,2-diamine)[β-ethyl (S)-aspartato-k2 N,O1]cobalt(III) bis-(perchlorate) monohydrate, (II), both [Co(C6H10N2O 4)(C2H8N2)2](ClO 4)2·H2O, are compared. In both structures, the ester group of the amino acid side chain is engaged only in intra-molecular hydrogen bonding to coordinated amine groups. This inter-action is stronger in (I) and correlates with previously observed diastereoisomeric equilibrium ratios for related metal complex systems in aqueous media. The two perchlorate anions of (II) are located on twofold axes. Both perchlorates in (I) and one of the perchlorates in (II) are affected by disorder. Both structures exhibit extensive three-dimensional hydrogen-bonding net-works.

AB - The structures of the diastereoisomers Δ (+)578-, (I), andΔ(-)578--bis-(ethane-1,2-diamine)[β-ethyl (S)-aspartato-k2 N,O1]cobalt(III) bis-(perchlorate) monohydrate, (II), both [Co(C6H10N2O 4)(C2H8N2)2](ClO 4)2·H2O, are compared. In both structures, the ester group of the amino acid side chain is engaged only in intra-molecular hydrogen bonding to coordinated amine groups. This inter-action is stronger in (I) and correlates with previously observed diastereoisomeric equilibrium ratios for related metal complex systems in aqueous media. The two perchlorate anions of (II) are located on twofold axes. Both perchlorates in (I) and one of the perchlorates in (II) are affected by disorder. Both structures exhibit extensive three-dimensional hydrogen-bonding net-works.

U2 - 10.1107/S0108270110036851

DO - 10.1107/S0108270110036851

M3 - Journal article

C2 - 21051807

AN - SCOPUS:78349267869

VL - 66

SP - m319-m322

JO - Acta crystallographica. Section C, Structural chemistry

JF - Acta crystallographica. Section C, Structural chemistry

SN - 2053-2296

IS - 11

ER -

ID: 240003101