The gas phase reactions of hydroxyl radicals with a series of nitroalkanes over the temperature range 240-400 K

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Standard

The gas phase reactions of hydroxyl radicals with a series of nitroalkanes over the temperature range 240-400 K. / Liu, Renzhang; Huie, Robert E.; Kurylo, Michael J.; Nielsen, Ole J.

In: Chemical Physics Letters, Vol. 167, No. 6, 13.04.1990, p. 519-523.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Liu, R, Huie, RE, Kurylo, MJ & Nielsen, OJ 1990, 'The gas phase reactions of hydroxyl radicals with a series of nitroalkanes over the temperature range 240-400 K', Chemical Physics Letters, vol. 167, no. 6, pp. 519-523. https://doi.org/10.1016/0009-2614(90)85462-L

APA

Liu, R., Huie, R. E., Kurylo, M. J., & Nielsen, O. J. (1990). The gas phase reactions of hydroxyl radicals with a series of nitroalkanes over the temperature range 240-400 K. Chemical Physics Letters, 167(6), 519-523. https://doi.org/10.1016/0009-2614(90)85462-L

Vancouver

Liu R, Huie RE, Kurylo MJ, Nielsen OJ. The gas phase reactions of hydroxyl radicals with a series of nitroalkanes over the temperature range 240-400 K. Chemical Physics Letters. 1990 Apr 13;167(6):519-523. https://doi.org/10.1016/0009-2614(90)85462-L

Author

Liu, Renzhang ; Huie, Robert E. ; Kurylo, Michael J. ; Nielsen, Ole J. / The gas phase reactions of hydroxyl radicals with a series of nitroalkanes over the temperature range 240-400 K. In: Chemical Physics Letters. 1990 ; Vol. 167, No. 6. pp. 519-523.

Bibtex

@article{4179cb450a9842d0bb5ee72eb8c3f485,
title = "The gas phase reactions of hydroxyl radicals with a series of nitroalkanes over the temperature range 240-400 K",
abstract = "Absolute rate constants were determined for the gas phase reactions of OH radicals with a series of nitroalkanes by the flash photolysis-resonance fluorescence technique. Experiments were performed at total pressures from 25 to 50 Torr using Ar as a diluent gas. Experiments with nitromethane and nitromethane-d3 at 296 K yielded rate constants of (1.58±0.09) × 10-14 and (0.9±0.04) × 10-14 cm3 molecule-1 s-1, respectively. Data from experiments over the temperature range 240-400 K for nitroethane, 1-nitropropane, 2-nitropropane, 1-nitrobutane, and 1-nitropentane were used to evaluate their Arrhenius parameters. The results are discussed in terms of the reaction mechanism, and are compared to previous literature data.",
author = "Renzhang Liu and Huie, {Robert E.} and Kurylo, {Michael J.} and Nielsen, {Ole J.}",
year = "1990",
month = apr,
day = "13",
doi = "10.1016/0009-2614(90)85462-L",
language = "English",
volume = "167",
pages = "519--523",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "6",

}

RIS

TY - JOUR

T1 - The gas phase reactions of hydroxyl radicals with a series of nitroalkanes over the temperature range 240-400 K

AU - Liu, Renzhang

AU - Huie, Robert E.

AU - Kurylo, Michael J.

AU - Nielsen, Ole J.

PY - 1990/4/13

Y1 - 1990/4/13

N2 - Absolute rate constants were determined for the gas phase reactions of OH radicals with a series of nitroalkanes by the flash photolysis-resonance fluorescence technique. Experiments were performed at total pressures from 25 to 50 Torr using Ar as a diluent gas. Experiments with nitromethane and nitromethane-d3 at 296 K yielded rate constants of (1.58±0.09) × 10-14 and (0.9±0.04) × 10-14 cm3 molecule-1 s-1, respectively. Data from experiments over the temperature range 240-400 K for nitroethane, 1-nitropropane, 2-nitropropane, 1-nitrobutane, and 1-nitropentane were used to evaluate their Arrhenius parameters. The results are discussed in terms of the reaction mechanism, and are compared to previous literature data.

AB - Absolute rate constants were determined for the gas phase reactions of OH radicals with a series of nitroalkanes by the flash photolysis-resonance fluorescence technique. Experiments were performed at total pressures from 25 to 50 Torr using Ar as a diluent gas. Experiments with nitromethane and nitromethane-d3 at 296 K yielded rate constants of (1.58±0.09) × 10-14 and (0.9±0.04) × 10-14 cm3 molecule-1 s-1, respectively. Data from experiments over the temperature range 240-400 K for nitroethane, 1-nitropropane, 2-nitropropane, 1-nitrobutane, and 1-nitropentane were used to evaluate their Arrhenius parameters. The results are discussed in terms of the reaction mechanism, and are compared to previous literature data.

UR - http://www.scopus.com/inward/record.url?scp=33646916037&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(90)85462-L

DO - 10.1016/0009-2614(90)85462-L

M3 - Journal article

AN - SCOPUS:33646916037

VL - 167

SP - 519

EP - 523

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 6

ER -

ID: 228197883