Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide
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Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide (DES), di‐n‐propyl sulfide (DPS), and di‐n‐butyl sulfide (DBS) have been determined at 295 ± 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of Cl atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained: (Formula Presented.)
Original language | English |
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Journal | International Journal of Chemical Kinetics |
Volume | 22 |
Issue number | 6 |
Pages (from-to) | 603-612 |
Number of pages | 10 |
ISSN | 0538-8066 |
DOIs | |
Publication status | Published - 1 Jan 1990 |
ID: 214273102