Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide
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Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide. / Nielsen, Ole J.; Sidebottom, Howard W.; Nelson, Linda; Rattigan, Oliver; Treacy, Jack J.; O'Farrell, Denis J.
In: International Journal of Chemical Kinetics, Vol. 22, No. 6, 01.01.1990, p. 603-612.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide
AU - Nielsen, Ole J.
AU - Sidebottom, Howard W.
AU - Nelson, Linda
AU - Rattigan, Oliver
AU - Treacy, Jack J.
AU - O'Farrell, Denis J.
PY - 1990/1/1
Y1 - 1990/1/1
N2 - Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide (DES), di‐n‐propyl sulfide (DPS), and di‐n‐butyl sulfide (DBS) have been determined at 295 ± 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of Cl atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained: (Formula Presented.)
AB - Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide (DES), di‐n‐propyl sulfide (DPS), and di‐n‐butyl sulfide (DBS) have been determined at 295 ± 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of Cl atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained: (Formula Presented.)
UR - http://www.scopus.com/inward/record.url?scp=0025445270&partnerID=8YFLogxK
U2 - 10.1002/kin.550220605
DO - 10.1002/kin.550220605
M3 - Journal article
AN - SCOPUS:0025445270
VL - 22
SP - 603
EP - 612
JO - International Journal of Chemical Kinetics
JF - International Journal of Chemical Kinetics
SN - 0538-8066
IS - 6
ER -
ID: 214273102