TY - BOOK

T1 - Stable Oxygen-18 and Deuterium Isotopes

T2 - Applications in a maritime-temperate lowland environment

AU - Müller, Sascha

N1 - Ph.d.-grad er opnået ved mundtligt forsvar 8. februar 2017

PY - 2016/12

Y1 - 2016/12

N2 - The application of stable Oxygen-18 (18O) and Deuterium (2H) isotopes, as a tracer for fluxes between different compartments of the water cycle was subject of the present PhD-thesis. During a three year period, temporal data from a wide range of water cycle constituents was collected from the Skjern River catchment, Denmark. The presented applications focused on studying the isotopic 'input signal' to the hydrosphere in the form of precipitation, the isotopic 'output signal' with its related dynamic processes at a coastal saltwater-freshwater interface (groundwater isotopes) and the temporal development within a given lowland headwater catchment (stream water isotopes).Based on our investigations on the precipitation isotopic composition a local meteoric water line (LMWL) was constructed and expressed as: δ2H=7.4 δ18O + 5.36‰. Moreover, we showed that under maritime temperature climate influence, humidity is the main driver for the temporal and spatial isotopic development and temperature plays only a secondary role.Based on our investigations at a coastal lagoon aquifer we could improve quantifications of seasonal saltwater-wedge dynamics, based on isotopic tracers combined with salinity. We can link the observed seasonal regression/transgression pattern to the inland recharge cycle, which is expressed in hydraulic head configuration and submarine groundwater discharge rates at the fieldsite. Nonetheless, those observed dynamics could not be simulated due to numerical limitations.By the use of different transit time estimation methods, comparing isotopic input signal (precipitation) to the isotopic output signal of a catchment (as stream isotopic compositions) mean transit times (MTT) for a headwater catchment were derived. Estimates suggested the stream water to be dominated by water of very young age. Those results are in contrast to earlier age estimations from groundwater samples just beneath the stream. We therefore suggest the conceptualization of the hydrological conditions at this headwater catchment to be revised.

AB - The application of stable Oxygen-18 (18O) and Deuterium (2H) isotopes, as a tracer for fluxes between different compartments of the water cycle was subject of the present PhD-thesis. During a three year period, temporal data from a wide range of water cycle constituents was collected from the Skjern River catchment, Denmark. The presented applications focused on studying the isotopic 'input signal' to the hydrosphere in the form of precipitation, the isotopic 'output signal' with its related dynamic processes at a coastal saltwater-freshwater interface (groundwater isotopes) and the temporal development within a given lowland headwater catchment (stream water isotopes).Based on our investigations on the precipitation isotopic composition a local meteoric water line (LMWL) was constructed and expressed as: δ2H=7.4 δ18O + 5.36‰. Moreover, we showed that under maritime temperature climate influence, humidity is the main driver for the temporal and spatial isotopic development and temperature plays only a secondary role.Based on our investigations at a coastal lagoon aquifer we could improve quantifications of seasonal saltwater-wedge dynamics, based on isotopic tracers combined with salinity. We can link the observed seasonal regression/transgression pattern to the inland recharge cycle, which is expressed in hydraulic head configuration and submarine groundwater discharge rates at the fieldsite. Nonetheless, those observed dynamics could not be simulated due to numerical limitations.By the use of different transit time estimation methods, comparing isotopic input signal (precipitation) to the isotopic output signal of a catchment (as stream isotopic compositions) mean transit times (MTT) for a headwater catchment were derived. Estimates suggested the stream water to be dominated by water of very young age. Those results are in contrast to earlier age estimations from groundwater samples just beneath the stream. We therefore suggest the conceptualization of the hydrological conditions at this headwater catchment to be revised.

UR - https://soeg.kb.dk/permalink/45KBDK_KGL/fbp0ps/alma99122097084705763

M3 - Ph.D. thesis

BT - Stable Oxygen-18 and Deuterium Isotopes

PB - Department of Geosciences and Natural Resource Management, Faculty of Science, University of Copenhagen

ER -