Investigation of cationic Claisen-type electrophilic rearrangements of amides
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Investigation of cationic Claisen-type electrophilic rearrangements of amides. / Padmanaban, Mohan; Carvalho, Luísa C.R.; Petkova, Desislava; Lee, Jiwoong; Santos, A. Sofia; Marques, M. Manuel B.; Maulide, Nuno.
I: Tetrahedron, Bind 71, Nr. 35, 2015, s. 5994-6005.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Investigation of cationic Claisen-type electrophilic rearrangements of amides
AU - Padmanaban, Mohan
AU - Carvalho, Luísa C.R.
AU - Petkova, Desislava
AU - Lee, Jiwoong
AU - Santos, A. Sofia
AU - Marques, M. Manuel B.
AU - Maulide, Nuno
PY - 2015
Y1 - 2015
N2 - Abstract Herein we report an extension of the electrophilic rearrangement of amides to the preparation of ??-prenyl-hydrocoumarins, indoles, isoquinolines and dihydro-isoquinolinones. An unusual competitive sulfonyl migration, uncovered upon attempted aza-Claisen rearrangement, is also described.
AB - Abstract Herein we report an extension of the electrophilic rearrangement of amides to the preparation of ??-prenyl-hydrocoumarins, indoles, isoquinolines and dihydro-isoquinolinones. An unusual competitive sulfonyl migration, uncovered upon attempted aza-Claisen rearrangement, is also described.
KW - Amides
KW - Hydrocoumarin
KW - Isoquinolinone
KW - Rearrangement
KW - oxa and aza-Claisen
U2 - 10.1016/j.tet.2015.06.027
DO - 10.1016/j.tet.2015.06.027
M3 - Journal article
VL - 71
SP - 5994
EP - 6005
JO - Tetrahedron
JF - Tetrahedron
SN - 0040-4020
IS - 35
ER -
ID: 172890738