Does Charge Influence the Response in Oxyanion Binding Europium(III) Complexes?
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Standard
Does Charge Influence the Response in Oxyanion Binding Europium(III) Complexes? / Hery, Simon; Grenier, Laura L. A.; Sørensen, Thomas J.
I: Analysis & Sensing, Bind 3, Nr. 4, e202200093, 2023.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Harvard
APA
Vancouver
Author
Bibtex
}
RIS
TY - JOUR
T1 - Does Charge Influence the Response in Oxyanion Binding Europium(III) Complexes?
AU - Hery, Simon
AU - Grenier, Laura L. A.
AU - Sørensen, Thomas J.
PY - 2023
Y1 - 2023
N2 - Through the synthesis of a positively charged europium complex, with a structure derived from the DO2A (1, 4, 7, 10-tetraazacyclododecane-1, 7-diacetic acid), we were able to explore the influence of charge on the interaction between coordinatively unsaturated lanthanide complexes and charged oxyanions. The data suggest that the positive charge of the lanthanide host does not allow better selectivity between the differently and negatively charged oxyanion guests. Although, binding constants seem greatly improved with charge for the α-hydroxycarboxylates investigated here.
AB - Through the synthesis of a positively charged europium complex, with a structure derived from the DO2A (1, 4, 7, 10-tetraazacyclododecane-1, 7-diacetic acid), we were able to explore the influence of charge on the interaction between coordinatively unsaturated lanthanide complexes and charged oxyanions. The data suggest that the positive charge of the lanthanide host does not allow better selectivity between the differently and negatively charged oxyanion guests. Although, binding constants seem greatly improved with charge for the α-hydroxycarboxylates investigated here.
U2 - 10.1002/anse.202200093
DO - 10.1002/anse.202200093
M3 - Journal article
VL - 3
JO - Analysis & Sensing
JF - Analysis & Sensing
SN - 2629-2742
IS - 4
M1 - e202200093
ER -
ID: 327792128