Synthesis and thermotropic phase behavior of four glycoglycerolipids
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Synthesis and thermotropic phase behavior of four glycoglycerolipids. / Hogendorf, Wouter Frederik Johan; Jagalski, Vivien; Günther-Pomorski, Thomas; Bols, Mikael; Cardenas Gomez, Marite; Pedersen, Christian Marcus.
In: Molecules, Vol. 18, No. 11, 2013, p. 13546-13573.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - Synthesis and thermotropic phase behavior of four glycoglycerolipids
AU - Hogendorf, Wouter Frederik Johan
AU - Jagalski, Vivien
AU - Günther-Pomorski, Thomas
AU - Bols, Mikael
AU - Cardenas Gomez, Marite
AU - Pedersen, Christian Marcus
PY - 2013
Y1 - 2013
N2 - Four glycoglycerolipids with different head groups have been synthesized and their physicochemical properties studied. The lengths of the head groups from a mono-saccharide to a trisaccharide, in addition to the anomeric stereochemistry for the smaller glycoglycerolipids, have been modified. The synthesis has been optimized to avoid glycerol epimerization and to allow up-scaling. The physicochemical properties of the glycoglycerolipids were studied and a strong de-mixing of the gel-phase, depending on the head-group, was observed.
AB - Four glycoglycerolipids with different head groups have been synthesized and their physicochemical properties studied. The lengths of the head groups from a mono-saccharide to a trisaccharide, in addition to the anomeric stereochemistry for the smaller glycoglycerolipids, have been modified. The synthesis has been optimized to avoid glycerol epimerization and to allow up-scaling. The physicochemical properties of the glycoglycerolipids were studied and a strong de-mixing of the gel-phase, depending on the head-group, was observed.
U2 - 10.3390/molecules181113546
DO - 10.3390/molecules181113546
M3 - Journal article
C2 - 24189295
VL - 18
SP - 13546
EP - 13573
JO - Molecules
JF - Molecules
SN - 1420-3049
IS - 11
ER -
ID: 95173595