Straightforward synthesis of a triazine-based porous carbon with high gas-uptake capacities

Research output: Contribution to journal › Journal article › Research › peer-review

Standard

Straightforward synthesis of a triazine-based porous carbon with high gas-uptake capacities. / Hu, Xinming; Chen, Qi; Zhao, Yan Chao; Laursen, Bo Wegge; Han, Bao Hang.

In: Journal of Materials Chemistry A, Vol. 2, No. 34, 2014, p. 14201-14208.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Hu, X, Chen, Q, Zhao, YC, Laursen, BW & Han, BH 2014, 'Straightforward synthesis of a triazine-based porous carbon with high gas-uptake capacities', Journal of Materials Chemistry A, vol. 2, no. 34, pp. 14201-14208. https://doi.org/10.1039/c4ta02073a

APA

Hu, X., Chen, Q., Zhao, Y. C., Laursen, B. W., & Han, B. H. (2014). Straightforward synthesis of a triazine-based porous carbon with high gas-uptake capacities. Journal of Materials Chemistry A, 2(34), 14201-14208. https://doi.org/10.1039/c4ta02073a

Vancouver

Hu X, Chen Q, Zhao YC, Laursen BW, Han BH. Straightforward synthesis of a triazine-based porous carbon with high gas-uptake capacities. Journal of Materials Chemistry A. 2014;2(34):14201-14208. https://doi.org/10.1039/c4ta02073a

Author

Hu, Xinming ; Chen, Qi ; Zhao, Yan Chao ; Laursen, Bo Wegge ; Han, Bao Hang. / Straightforward synthesis of a triazine-based porous carbon with high gas-uptake capacities. In: Journal of Materials Chemistry A. 2014 ; Vol. 2, No. 34. pp. 14201-14208.

Bibtex

@article{c1e3535ba6e742ca9b2afbf77d00570e,
title = "Straightforward synthesis of a triazine-based porous carbon with high gas-uptake capacities",
abstract = "A triazine-based porous carbon material (TPC-1) was prepared directly from a fluorinated aromatic nitrile in molten zinc chloride. Trimerization of the nitrile and subsequent defluorination carbonization of the polymeric network result in the formation of TPC-1. The defluorination process is reversible and can etch the polymeric network to release CFn, thereby generating additional porosity and rendering TPC-1 a nitrogen-rich porous material. TPC-1 shows a high BET surface area of 1940 m2 g-1 and contains both micropores and mesopores, which facilitate the diffusion and adsorption of gas molecules. Gas adsorption experiments demonstrate outstanding uptake capacities of TPC-1 for CO2 (4.9 mmol g-1, 273 K and 1.0 bar), CH4 (3.9 mmol g-1, 273 K and 1.0 bar), and H 2 (10.1 mmol g-1, 77 K and 1.0 bar). This straightforward synthesis procedure provides an alternative pathway to prepare high-performance porous carbon materials. This journal is",
author = "Xinming Hu and Qi Chen and Zhao, {Yan Chao} and Laursen, {Bo Wegge} and Han, {Bao Hang}",
year = "2014",
doi = "10.1039/c4ta02073a",
language = "English",
volume = "2",
pages = "14201--14208",
journal = "Journal of Materials Chemistry A",
issn = "2050-7488",
publisher = "RSC Publications",
number = "34",

}

RIS

TY - JOUR

T1 - Straightforward synthesis of a triazine-based porous carbon with high gas-uptake capacities

AU - Hu, Xinming

AU - Chen, Qi

AU - Zhao, Yan Chao

AU - Laursen, Bo Wegge

AU - Han, Bao Hang

PY - 2014

Y1 - 2014

N2 - A triazine-based porous carbon material (TPC-1) was prepared directly from a fluorinated aromatic nitrile in molten zinc chloride. Trimerization of the nitrile and subsequent defluorination carbonization of the polymeric network result in the formation of TPC-1. The defluorination process is reversible and can etch the polymeric network to release CFn, thereby generating additional porosity and rendering TPC-1 a nitrogen-rich porous material. TPC-1 shows a high BET surface area of 1940 m2 g-1 and contains both micropores and mesopores, which facilitate the diffusion and adsorption of gas molecules. Gas adsorption experiments demonstrate outstanding uptake capacities of TPC-1 for CO2 (4.9 mmol g-1, 273 K and 1.0 bar), CH4 (3.9 mmol g-1, 273 K and 1.0 bar), and H 2 (10.1 mmol g-1, 77 K and 1.0 bar). This straightforward synthesis procedure provides an alternative pathway to prepare high-performance porous carbon materials. This journal is

AB - A triazine-based porous carbon material (TPC-1) was prepared directly from a fluorinated aromatic nitrile in molten zinc chloride. Trimerization of the nitrile and subsequent defluorination carbonization of the polymeric network result in the formation of TPC-1. The defluorination process is reversible and can etch the polymeric network to release CFn, thereby generating additional porosity and rendering TPC-1 a nitrogen-rich porous material. TPC-1 shows a high BET surface area of 1940 m2 g-1 and contains both micropores and mesopores, which facilitate the diffusion and adsorption of gas molecules. Gas adsorption experiments demonstrate outstanding uptake capacities of TPC-1 for CO2 (4.9 mmol g-1, 273 K and 1.0 bar), CH4 (3.9 mmol g-1, 273 K and 1.0 bar), and H 2 (10.1 mmol g-1, 77 K and 1.0 bar). This straightforward synthesis procedure provides an alternative pathway to prepare high-performance porous carbon materials. This journal is

U2 - 10.1039/c4ta02073a

DO - 10.1039/c4ta02073a

M3 - Journal article

AN - SCOPUS:84905579560

VL - 2

SP - 14201

EP - 14208

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

SN - 2050-7488

IS - 34

ER -

ID: 131019569