NMR insights on the properties of ZnCl2 molten salt hydrate medium through its interaction with SnCl4 and fructose
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NMR insights on the properties of ZnCl2 molten salt hydrate medium through its interaction with SnCl4 and fructose. / Qiao, Yan; Pedersen, Christian Marcus; Wang, Yingxiong; Hou, Xianglin.
In: A C S Sustainable Chemistry & Engineering, Vol. 2, No. 11, 2014, p. 2576-2581.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - NMR insights on the properties of ZnCl2 molten salt hydrate medium through its interaction with SnCl4 and fructose
AU - Qiao, Yan
AU - Pedersen, Christian Marcus
AU - Wang, Yingxiong
AU - Hou, Xianglin
PY - 2014
Y1 - 2014
N2 - The solvent properties of ZnCl2 molten salt medium and its synergic effect with the Lewis acid catalyst, Sn4+, for biomass conversion, were investigated by nuclear magnetic resonance. The tautomeric distribution of fructose in the ZnCl2 molten salt medium was examined, and its effect for humins formation during the biomass conversion was evaluated. The ion complex composed by Sn4+ and Zn2+ indicated that there is a synergic catalytic effect between these two Lewis acid ions. 13C NMR spectra of fructose in different ZnCl2 molten salt hydrate concentrations revealed that the concentration of β-furanose and α-furanose tautomers, which lead to 5-HMF, were significantly decreased with increased salt concentration. Meanwhile the β-pyranose tautomer, which is correlated with humins formation, was increased significantly.
AB - The solvent properties of ZnCl2 molten salt medium and its synergic effect with the Lewis acid catalyst, Sn4+, for biomass conversion, were investigated by nuclear magnetic resonance. The tautomeric distribution of fructose in the ZnCl2 molten salt medium was examined, and its effect for humins formation during the biomass conversion was evaluated. The ion complex composed by Sn4+ and Zn2+ indicated that there is a synergic catalytic effect between these two Lewis acid ions. 13C NMR spectra of fructose in different ZnCl2 molten salt hydrate concentrations revealed that the concentration of β-furanose and α-furanose tautomers, which lead to 5-HMF, were significantly decreased with increased salt concentration. Meanwhile the β-pyranose tautomer, which is correlated with humins formation, was increased significantly.
KW - 5-HMF
KW - Fructose
KW - Molten salt hydrate medium
KW - NMR
KW - ZnCl
U2 - 10.1021/sc5004693
DO - 10.1021/sc5004693
M3 - Journal article
AN - SCOPUS:84908537543
VL - 2
SP - 2576
EP - 2581
JO - A C S Sustainable Chemistry & Engineering
JF - A C S Sustainable Chemistry & Engineering
SN - 2168-0485
IS - 11
ER -
ID: 131020706