The mixed-valent (μ-nitrido)-dimanganese complex anion [(CN)5Mn(v)(μ- N)Mn(II)(CN)5]6-

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Localized valencies are displayed by the Mn(v)Mn(II) complex ion 1. This is the key finding from X-ray structure analysis, as well as vibrational and EPR spectroscopic investigations on 1 obtained by the reaction of manganese(II) and [Mn(v)(N)(CN)5]3- salts in aqueous 1M NaCN solution. Remarkably, the asymmetry is induced by the nitrogen atom bridge.

TidsskriftAngewandte Chemie - International Edition
Udgave nummer18
Sider (fra-til)2766-2768
Antal sider3
StatusUdgivet - 17 sep. 1999

ID: 240004097