Cyclo-Tetra-μ-fluorido-1:2κ2F;2:3κ2 F;3:4κ2 F;1:4κ2 F-octanitrato- 1κ8 O,O′;3κ8 O,O′-tetrakis-(1,10- phenanthroline)-2κ4 N,N′;4κ4 N,N′-2,4-dichromium(III)-1,3-dineodymium(III) methanol tetra-solvate monohydrate

Publikation: Bidrag til tidsskriftTidsskriftartikelfagfællebedømt

Standard

Cyclo-Tetra-μ-fluorido-1:2κ2F;2:3κ2 F;3:4κ2 F;1:4κ2 F-octanitrato- 1κ8 O,O′;3κ8 O,O′-tetrakis-(1,10- phenanthroline)-2κ4 N,N′;4κ4 N,N′-2,4-dichromium(III)-1,3-dineodymium(III) methanol tetra-solvate monohydrate. / Birk, Torben; Schau-Magnussen, Magnus; Weyhermüller, Thomas; Bendix, Jesper.

I: Acta Crystallographica Section E: Structure Reports Online, Bind 67, Nr. 11, 01.11.2011, s. m1561-m1562.

Publikation: Bidrag til tidsskriftTidsskriftartikelfagfællebedømt

Harvard

Birk, T, Schau-Magnussen, M, Weyhermüller, T & Bendix, J 2011, 'Cyclo-Tetra-μ-fluorido-1:2κ2F;2:3κ2 F;3:4κ2 F;1:4κ2 F-octanitrato- 1κ8 O,O′;3κ8 O,O′-tetrakis-(1,10- phenanthroline)-2κ4 N,N′;4κ4 N,N′-2,4-dichromium(III)-1,3-dineodymium(III) methanol tetra-solvate monohydrate', Acta Crystallographica Section E: Structure Reports Online, bind 67, nr. 11, s. m1561-m1562. https://doi.org/10.1107/S1600536811042383

APA

Birk, T., Schau-Magnussen, M., Weyhermüller, T., & Bendix, J. (2011). Cyclo-Tetra-μ-fluorido-1:2κ2F;2:3κ2 F;3:4κ2 F;1:4κ2 F-octanitrato- 1κ8 O,O′;3κ8 O,O′-tetrakis-(1,10- phenanthroline)-2κ4 N,N′;4κ4 N,N′-2,4-dichromium(III)-1,3-dineodymium(III) methanol tetra-solvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 67(11), m1561-m1562. https://doi.org/10.1107/S1600536811042383

Vancouver

Birk T, Schau-Magnussen M, Weyhermüller T, Bendix J. Cyclo-Tetra-μ-fluorido-1:2κ2F;2:3κ2 F;3:4κ2 F;1:4κ2 F-octanitrato- 1κ8 O,O′;3κ8 O,O′-tetrakis-(1,10- phenanthroline)-2κ4 N,N′;4κ4 N,N′-2,4-dichromium(III)-1,3-dineodymium(III) methanol tetra-solvate monohydrate. Acta Crystallographica Section E: Structure Reports Online. 2011 nov. 1;67(11):m1561-m1562. https://doi.org/10.1107/S1600536811042383

Author

Birk, Torben ; Schau-Magnussen, Magnus ; Weyhermüller, Thomas ; Bendix, Jesper. / Cyclo-Tetra-μ-fluorido-1:2κ2F;2:3κ2 F;3:4κ2 F;1:4κ2 F-octanitrato- 1κ8 O,O′;3κ8 O,O′-tetrakis-(1,10- phenanthroline)-2κ4 N,N′;4κ4 N,N′-2,4-dichromium(III)-1,3-dineodymium(III) methanol tetra-solvate monohydrate. I: Acta Crystallographica Section E: Structure Reports Online. 2011 ; Bind 67, Nr. 11. s. m1561-m1562.

Bibtex

@article{af5f587959804a1c83e6edd1c70e3d71,
title = "Cyclo-Tetra-μ-fluorido-1:2κ2F;2:3κ2 F;3:4κ2 F;1:4κ2 F-octanitrato- 1κ8 O,O′;3κ8 O,O′-tetrakis-(1,10- phenanthroline)-2κ4 N,N′;4κ4 N,N′-2,4-dichromium(III)-1,3-dineodymium(III) methanol tetra-solvate monohydrate",
abstract = "In the title compound, [Cr2Nd2F4(NO 2)8(C12H8N2) 4]·4CH3OH·H2O, two cis-difluoridobis(1,10-phenanthroline)chromium(III) fragments containing octa-hedrally coordinated chromium(III) bridge via fluoride ions to two tetra-nitratoneodymate(III) fragments, forming an uncharged tetra-nuclear square-like core. The fluoride bridges are fairly linear, with Cr - F - Nd angles of 168.74 (8)°. Cr - F bond lengths are 1.8815 (15) {\AA}, slightly elongated compared to those of the parent chromium(III) complex, which has bond lengths ranging from 1.8444 (10) to 1.8621 (10) {\AA}. The tetra-nuclear complex is centered at a fourfold rotoinversion axis, with the Cr and Nd atoms situated on two perpendicular twofold rotation axes. The uncoordinated water molecule resides on a fourfold rotation axis. The four methanol solvent molecules are located around this axis, forming a cyclic hydrogen-bonded arrangement. The title compound is the first structurally characterized example of unsupported fluoride bridges between lanthanide and transition metal ions.",
author = "Torben Birk and Magnus Schau-Magnussen and Thomas Weyherm{\"u}ller and Jesper Bendix",
year = "2011",
month = nov,
day = "1",
doi = "10.1107/S1600536811042383",
language = "English",
volume = "67",
pages = "m1561--m1562",
journal = "Acta Crystallographica Section E: Crystallographic Communications",
issn = "1600-5368",
publisher = "Wiley-Blackwell",
number = "11",

}

RIS

TY - JOUR

T1 - Cyclo-Tetra-μ-fluorido-1:2κ2F;2:3κ2 F;3:4κ2 F;1:4κ2 F-octanitrato- 1κ8 O,O′;3κ8 O,O′-tetrakis-(1,10- phenanthroline)-2κ4 N,N′;4κ4 N,N′-2,4-dichromium(III)-1,3-dineodymium(III) methanol tetra-solvate monohydrate

AU - Birk, Torben

AU - Schau-Magnussen, Magnus

AU - Weyhermüller, Thomas

AU - Bendix, Jesper

PY - 2011/11/1

Y1 - 2011/11/1

N2 - In the title compound, [Cr2Nd2F4(NO 2)8(C12H8N2) 4]·4CH3OH·H2O, two cis-difluoridobis(1,10-phenanthroline)chromium(III) fragments containing octa-hedrally coordinated chromium(III) bridge via fluoride ions to two tetra-nitratoneodymate(III) fragments, forming an uncharged tetra-nuclear square-like core. The fluoride bridges are fairly linear, with Cr - F - Nd angles of 168.74 (8)°. Cr - F bond lengths are 1.8815 (15) Å, slightly elongated compared to those of the parent chromium(III) complex, which has bond lengths ranging from 1.8444 (10) to 1.8621 (10) Å. The tetra-nuclear complex is centered at a fourfold rotoinversion axis, with the Cr and Nd atoms situated on two perpendicular twofold rotation axes. The uncoordinated water molecule resides on a fourfold rotation axis. The four methanol solvent molecules are located around this axis, forming a cyclic hydrogen-bonded arrangement. The title compound is the first structurally characterized example of unsupported fluoride bridges between lanthanide and transition metal ions.

AB - In the title compound, [Cr2Nd2F4(NO 2)8(C12H8N2) 4]·4CH3OH·H2O, two cis-difluoridobis(1,10-phenanthroline)chromium(III) fragments containing octa-hedrally coordinated chromium(III) bridge via fluoride ions to two tetra-nitratoneodymate(III) fragments, forming an uncharged tetra-nuclear square-like core. The fluoride bridges are fairly linear, with Cr - F - Nd angles of 168.74 (8)°. Cr - F bond lengths are 1.8815 (15) Å, slightly elongated compared to those of the parent chromium(III) complex, which has bond lengths ranging from 1.8444 (10) to 1.8621 (10) Å. The tetra-nuclear complex is centered at a fourfold rotoinversion axis, with the Cr and Nd atoms situated on two perpendicular twofold rotation axes. The uncoordinated water molecule resides on a fourfold rotation axis. The four methanol solvent molecules are located around this axis, forming a cyclic hydrogen-bonded arrangement. The title compound is the first structurally characterized example of unsupported fluoride bridges between lanthanide and transition metal ions.

UR - http://www.scopus.com/inward/record.url?scp=84455190837&partnerID=8YFLogxK

U2 - 10.1107/S1600536811042383

DO - 10.1107/S1600536811042383

M3 - Journal article

AN - SCOPUS:84455190837

VL - 67

SP - m1561-m1562

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

SN - 1600-5368

IS - 11

ER -

ID: 240002976